Angular separation ≈ 0.018° (about 1.08′); yes, the lines are resolved, because the grating has 1250 lines while only about 983 are needed.
Grating element:
\[d = \frac{0.25\times10^{-2}\ \text{m}}{1250} = 2\times10^{-6}\ \text{m}\]
First order (n = 1): \(d\sin\theta = n\lambda\)
\[\sin\theta_1 = \frac{5895\times10^{-10}}{2\times10^{-6}} = 0.29475\]
\[\theta_1 = 17.143^\circ\]
\[\sin\theta_2 = \frac{5901\times10^{-10}}{2\times10^{-6}} = 0.29505\]
\[\theta_2 = 17.161^\circ\]
\[\Delta\theta = 0.018^\circ \approx 1.08'\]
Resolution: resolving power needed is
\[\frac{\lambda}{d\lambda} = \frac{5895}{6} \approx 983\]
Resolving power of the grating in first order is \(nN = 1 \times 1250 = 1250\), where \(N\) is the total number of lines.
Since 1250 > 983, the two sodium lines can be seen as separate lines in the first order.