Derive an expression for radius of nth Bohr orbit.
Q.6 Derive an expression for radius of nth Bohr orbit.
Q.6 Derive an expression for radius of nth Bohr orbit.
Best answer
Answer: \(r_n = \dfrac{\varepsilon_0 h^2 n^2}{\pi m Z e^2}\) (for hydrogen \(Z = 1\)).
Consider an electron of mass \(m\), charge \(e\) moving with speed \(v_n\) in the \(n\)th circular orbit of radius \(r_n\) around a nucleus of charge \(Ze\).
(1) The electrostatic attraction provides the centripetal force:
\[\frac{m v_n^2}{r_n} = \frac{1}{4\pi\varepsilon_0}\frac{Ze^2}{r_n^2} \quad\Rightarrow\quad m v_n^2 r_n = \frac{Ze^2}{4\pi\varepsilon_0} \qquad (1)\](2) Bohr’s quantum condition: angular momentum is an integral multiple of \(h/2\pi\):
\[m v_n r_n = \frac{nh}{2\pi} \quad\Rightarrow\quad v_n = \frac{nh}{2\pi m r_n} \qquad (2)\]Substituting (2) in (1):
\[m\left(\frac{nh}{2\pi m r_n}\right)^2 r_n = \frac{Ze^2}{4\pi\varepsilon_0} \Rightarrow \frac{n^2h^2}{4\pi^2 m r_n} = \frac{Ze^2}{4\pi\varepsilon_0}\]\[\boxed{r_n = \frac{\varepsilon_0 h^2 n^2}{\pi m Z e^2}}\]So \(r_n \propto n^2\). For hydrogen in the ground state (\(n = 1\), \(Z = 1\)) this gives the Bohr radius \(r_1 \approx 0.53\) Å.
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