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Answer: Oxygen in H2O has 2 bond pairs and 2 lone pairs (tetrahedral electron-pair arrangement); the molecule is angular (bent / V-shaped) with H–O–H bond angle 104.5°.

Electron distribution around oxygen:

  • Electronic configuration of O (Z = 8): 1s2 2s2 2p4. It has 6 valence electrons.
  • Oxygen shares one electron with each of the two H atoms, forming two O–H single bonds (2 bond pairs).
  • The remaining 4 valence electrons stay on oxygen as 2 lone pairs. Thus oxygen has 4 electron pairs (8 electrons) around it, i.e. a complete octet.
  • Lewis structure: H : Ö : H, i.e. H–O–H with two lone pairs (four dots) on the oxygen atom.

Shape:

  • Oxygen is sp3 hybridized; the four electron pairs point towards the corners of a tetrahedron (electron-pair geometry is tetrahedral).
  • Only two corners are occupied by H atoms; the other two are lone pairs. Lone pair–lone pair repulsion > lone pair–bond pair > bond pair–bond pair repulsion, so the O–H bonds are pushed closer.
  • Hence the shape of the water molecule is angular (bent or V-shaped), not tetrahedral.

H–O–H bond angle: 104.5° (less than the tetrahedral angle 109.5° because of the two lone pairs).

Doubtly · 18 Oct 2021 Report
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Answer: The oxygen atom in water has 2 bond pairs and 2 lone pairs. The molecule is bent (V-shaped or angular), and the H–O–H bond angle is 104.5°.

Electron distribution: Oxygen (\(Z = 8\), configuration 2, 6) has 6 valence electrons. It shares one electron with each of the two hydrogen atoms, forming two O–H covalent bonds. The remaining 4 electrons stay on oxygen as 2 lone pairs. So around oxygen there are 4 electron pairs: 2 bond pairs and 2 lone pairs.

Electron-dot (Lewis) structure: H : Ö : H, with two lone pairs on O (one above and one below).

Shape: The four electron pairs arrange themselves tetrahedrally (oxygen is \(\mathrm{sp^3}\) hybridised). But the shape of a molecule is decided by the positions of the atoms only. With two positions occupied by lone pairs, the three atoms H–O–H form a bent (V-shaped) molecule.

Bond angle: Lone pairs repel more strongly than bond pairs (lone pair–lone pair > lone pair–bond pair > bond pair–bond pair). This pushes the two O–H bonds closer, so the angle decreases from the tetrahedral 109.5° to 104.5°.

Doubtly AI · 23 Oct 2026 AI-verified · Oct 2026 Report
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