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OrderMolecularity
It is the sum of the powers of the concentration terms in the experimentally determined rate law.It is the number of reactant molecules (atoms/ions) taking part in an elementary step.
It is determined experimentally.It is a theoretical concept based on the mechanism.
It can be zero, a whole number or a fraction.It is always a whole number (1, 2 or rarely 3), never zero or fractional.
It applies to the overall reaction.It applies to each elementary step; it has no meaning for a complex overall reaction.
Doubtly AI · 28 Oct 2026 AI-verified · Oct 2026 Report
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