Convert – (Indicate by reaction)(a) Acetic acid to ethyl acetate(b) Acetaldehyde to acetaldoxime(c) Acetone to propane
Q.22 Convert – (Indicate by reaction)
(a) Acetic acid to ethyl acetate
(b) Acetaldehyde to acetaldoxime
(c) Acetone to propane
Q.22 Convert – (Indicate by reaction)
(a) Acetic acid to ethyl acetate
(b) Acetaldehyde to acetaldoxime
(c) Acetone to propane
Best answer
Answer:
(a) Esterification: CH3COOH + C2H5OH ⇌ (conc. H2SO4, Δ) CH3COOC2H5 + H2O (acetic acid + ethanol → ethyl acetate).
(b) With hydroxylamine: CH3CHO + H2N–OH —(weakly acidic medium)→ CH3CH=N–OH + H2O (acetaldoxime).
(c) Clemmensen reduction: CH3COCH3 + 4[H] —(Zn-Hg, conc. HCl)→ CH3CH2CH3 + H2O (propane). (Wolff–Kishner reduction with NH2NH2/KOH in ethylene glycol also gives propane.)
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