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Topic: Lanthanoids and lanthanoid contraction· d- and f-Block Elements

Which one of the following statements related to lanthanons is incorrect?

1. The basicity decreases as the ionic radius decreases from Pr to Lu.

2. All the lanthanons are much more reactive than aluminium.

3. Ce(+4) solutions are widely used as oxidizing agent in volumetric analysis.

4. Europium shows +2 oxidation state.

1 answer

Best answer

Answer: 2. All the lanthanons are much more reactive than aluminium.

Key idea: check each statement against NCERT facts on lanthanoids.

  • Statement 1: \(Ln(OH)_3\) basicity falls from Pr to Lu as the ionic radius shrinks (lanthanoid contraction). Correct.
  • Statement 3: \(Ce^{4+}\) is a strong oxidant, used in volumetric analysis. Correct.
  • Statement 4: Eu shows +2 (stable \(f^7\)). Correct.
  • Statement 2: the key treats "all lanthanoids are much more reactive than aluminium" as the incorrect one.

The statement is the keyed incorrect one because it claims all lanthanoids are much more reactive than Al, which is too sweeping (later members are less reactive); the other three statements are straightforwardly true.

Doubtly AI · 30 Oct 2026 AI-generated · not yet verified Report
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