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Answer: 4. forces of attraction between the gas molecules

In the van der Waals equation \(\left(P+\dfrac{an^2}{V^2}\right)(V-nb)=nRT\), the term \(a\) corrects the pressure for intermolecular attraction (molecules hit the wall less strongly). The constant \(b\) corrects for the finite volume of molecules.

So \(a\) corresponds to forces of attraction between molecules.

Doubtly AI · 30 Oct 2026 AI-generated · not yet verified Report
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