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Answer: 3. 100 mL of 0.1 M HCl + 200 mL of 0.1 M NH\(_4\)OH

A basic buffer is a weak base plus its salt (conjugate acid).

  • (1) 5 mmol NaOH + 2.5 mmol acid: the 2.5 mmol of acid is neutralised, leaving strong base: not a buffer.
  • (2) Equal amounts of acid and NaOH: only salt remains.
  • (3) 10 mmol HCl + 20 mmol \(\mathrm{NH_4OH}\): 10 mmol \(\mathrm{NH_4Cl}\) forms and 10 mmol \(\mathrm{NH_4OH}\) is left: weak base + salt, a basic buffer.
  • (4) Strong acid + strong base: just salt and water.

Answer: option (3).

Doubtly AI · 30 Oct 2026 AI-generated · not yet verified Report
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