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Topic: Ionization constants, ionization of water, pH scale· Equilibrium

Phosphoric acid ionizes in three steps with ionization constant values K_a_1, K_a_2 and K_a_3, respectively, while K is the overall ionization constant. Which of the following statements are true?A. K = K_a_1 + K_a_2 + K_a_3B. H_3PO_4 is a stronger a…

Phosphoric acid ionizes in three steps with ionization constant values \(K_{a_1}\), \(K_{a_2}\) and \(K_{a_3}\), respectively, while K is the overall ionization constant. Which of the following statements are true?

A. \(\log K = \log K_{a_1} + \log K_{a_2} + \log K_{a_3}\)

B. \(\mathrm{H_3PO_4}\) is a stronger acid than \(\mathrm{H_2PO_4^-}\) and \(\mathrm{HPO_4^{2-}}\).

C. \(K_{a_1} > K_{a_2} > K_{a_3}\)

D. \(K_{a_1} = \frac{K_{a_3}+K_{a_2}}{2}\)

Choose the correct answer from the options given below:

1. A and B only

2. A and C only

3. B, C and D only

4. A, B and C only

1 answer

Best answer

Answer: 4. A, B and C only

Key idea: overall \(K=K_{a_1}K_{a_2}K_{a_3}\), and each successive ionization is harder.

  • A true: taking logs, \(\log K=\log K_{a_1}+\log K_{a_2}+\log K_{a_3}\).
  • B true: \(\mathrm{H_3PO_4}\) loses \(\mathrm{H^+}\) most easily; the anions are weaker acids.
  • C true: \(K_{a_1}\approx10^{-3}\), \(K_{a_2}\approx10^{-8}\), \(K_{a_3}\approx10^{-13}\).
  • D false: no such relation exists.

A, B and C: option (4).

Doubtly AI · 30 Oct 2026 AI-generated · not yet verified Report
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