Which one of the following reactions does NOT belong to "Lassaigne's test"?
1. \(\mathrm{Na + C + N \xrightarrow{\Delta} NaCN}\)
2. \(\mathrm{2Na + S \xrightarrow{\Delta} Na_2S}\)
3. \(\mathrm{Na + X \xrightarrow{\Delta} NaX}\)
4. \(\mathrm{2CuO + C \xrightarrow{\Delta} 2Cu + CO_2}\)