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Topic: Qualitative analysis: detection of N, S, P, halogens· Purification and Characterisation of Organic Compounds

Which one of the following reactions does NOT belong to "Lassaigne's test"?

1. \(\mathrm{Na + C + N \xrightarrow{\Delta} NaCN}\)

2. \(\mathrm{2Na + S \xrightarrow{\Delta} Na_2S}\)

3. \(\mathrm{Na + X \xrightarrow{\Delta} NaX}\)

4. \(\mathrm{2CuO + C \xrightarrow{\Delta} 2Cu + CO_2}\)

1 answer

Best answer

Answer: 4. \(\mathrm{2CuO + C \xrightarrow{\Delta} 2Cu + CO_2}\)

Key idea: Lassaigne's test fuses the organic compound with sodium to convert N, S and halogens into ionic \(\mathrm{NaCN}\), \(\mathrm{Na_2S}\) and NaX.

Options (1), (2), (3) are these fusion reactions. \(\mathrm{2CuO+C\to2Cu+CO_2}\) is the carbon-detection step of the copper(II) oxide test (Liebig), not Lassaigne's test. Option (4).

Doubtly AI · 30 Oct 2026 AI-generated · not yet verified Report
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