Draw all possible structural formulae of compounds from their molecular formula given below.
Draw all possible structural formulae of compounds from their molecular formula given below.
(i) C3H8 (ii) C4H10 (iii) C3H4
Draw all possible structural formulae of compounds from their molecular formula given below.
(i) C3H8 (ii) C4H10 (iii) C3H4
Best answer
Answer: (i) C3H8: one structure (propane); (ii) C4H10: two structures (n-butane and isobutane); (iii) C3H4: propyne, propadiene (and cyclopropene).
(i) C3H8 — Propane (only one possible structure)
\(\text{CH}_3-\text{CH}_2-\text{CH}_3\)
(ii) C4H10 (two structural isomers)
1. n-Butane (straight chain): \(\text{CH}_3-\text{CH}_2-\text{CH}_2-\text{CH}_3\)
2. Isobutane (2-methylpropane, branched chain): \(\text{CH}_3-\underset{\displaystyle \text{CH}_3}{\underset{|}{\text{CH}}}-\text{CH}_3\)
(iii) C3H4
1. Propyne (triple bond): \(\text{CH}\equiv\text{C}-\text{CH}_3\)
2. Propadiene (two double bonds): \(\text{CH}_2=\text{C}=\text{CH}_2\)
3. Cyclopropene: a three-membered ring of carbon atoms with one C=C double bond (two CH groups joined by the double bond, and one CH2 group).
Check: each carbon has 4 bonds and each hydrogen 1 bond in every structure.



Answer: C₃H₈ has 1 structure; C₄H₁₀ has 2 (butane and 2-methylpropane); C₃H₄ has 3 (propyne, propadiene and cyclopropene).
(i) \(\mathrm{C_3H_8}\): only one structure is possible.
(ii) \(\mathrm{C_4H_{10}}\): two structures (chain isomers).
(iii) \(\mathrm{C_3H_4}\): this formula has two fewer pairs of H than propane, so it has a triple bond, two double bonds, or one double bond in a ring.
When drawing the full structural formulae, show each carbon with four bonds and each hydrogen with one bond.
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