Write the differences between lanthanoids and actinoids.
Q.5 Write the differences between lanthanoids and actinoids.
Q.5 Write the differences between lanthanoids and actinoids.
Best answer
Answer: Lanthanoids fill 4f orbitals; actinoids fill 5f orbitals and differ as below.
| Lanthanoids | Actinoids |
|---|---|
| The differentiating electron enters 4f orbitals. | The differentiating electron enters 5f orbitals. |
| Common oxidation state is +3; a few show +2 and +4. | Show +3 and many higher oxidation states (+4, +5, +6, +7), because 5f, 6d and 7s energies are close. |
| Except promethium, they are non-radioactive. | All are radioactive. |
| Less tendency to form complexes; do not form oxo-cations. | Greater tendency to form complexes; form oxo-cations such as UO22+, PuO22+. |
| Lanthanoid contraction is smaller. | Actinoid contraction is larger (poor shielding by 5f electrons). |
(Any four points.)
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