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Answer: Lanthanoids fill 4f orbitals; actinoids fill 5f orbitals and differ as below.

LanthanoidsActinoids
The differentiating electron enters 4f orbitals.The differentiating electron enters 5f orbitals.
Common oxidation state is +3; a few show +2 and +4.Show +3 and many higher oxidation states (+4, +5, +6, +7), because 5f, 6d and 7s energies are close.
Except promethium, they are non-radioactive.All are radioactive.
Less tendency to form complexes; do not form oxo-cations.Greater tendency to form complexes; form oxo-cations such as UO22+, PuO22+.
Lanthanoid contraction is smaller.Actinoid contraction is larger (poor shielding by 5f electrons).

(Any four points.)

Doubtly AI · 28 Oct 2026 AI-verified · Oct 2026 Report
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