Write chemical reactions for the preparation of phenol from isopropyl benzene.
Q.13 Write chemical reactions for the preparation of phenol from isopropyl benzene.
Q.13 Write chemical reactions for the preparation of phenol from isopropyl benzene.
Best answer
Answer: (Cumene process)
Step 1: Isopropyl benzene (cumene) is oxidised by air at about 400 K (in presence of a little alkali) to cumene hydroperoxide:
C6H5–CH(CH3)2 + O2 → C6H5–C(CH3)2–O–OH
Step 2: Cumene hydroperoxide is warmed with dilute acid (H3O+), which rearranges and hydrolyses it to phenol and acetone:
C6H5–C(CH3)2–O–OH —(H3O+)→ C6H5OH + CH3COCH3
Acetone is obtained as a valuable by-product.
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