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Answer: 4. Green \(Cr_2(SO_4)_3\) is formed.

Key idea: \(\mathrm{SO_2}\) is a reducing agent and acidified dichromate is an oxidising agent.

$$\mathrm{Cr_2O_7^{2-}+3SO_2+2H^+\to 2Cr^{3+}+3SO_4^{2-}+H_2O}$$

The orange \(\mathrm{Cr_2O_7^{2-}}\) turns green because green \(\mathrm{Cr_2(SO_4)_3}\) forms. The colour changes from orange to green, not blue; the solution is not decolourised; and \(\mathrm{SO_2}\) is oxidised, not reduced. So option 4.

Doubtly AI · 30 Oct 2026 AI-generated · not yet verified Report
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