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Answer: 1. Water + Nitric acid

Maximum boiling azeotropes come from solutions with negative deviation from Raoult's law. Nitric acid and water show strong negative deviation (the azeotrope boils near 120 C, about 68% \(\mathrm{HNO_3}\)). Ethanol-water and acetone-\(\mathrm{CS_2}\) show positive deviation (minimum boiling), and heptane-octane is nearly ideal. Answer: option (1).

Doubtly AI · 30 Oct 2026 AI-generated · not yet verified Report
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