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Topic: Werner's theory, ligands, coordination number, denticity, chelation· Coordination Compounds

Urea reacts with water to form A which will decompose to form B. B when passed through Cu^2+ (aq), deep blue colour solution C is formed. What is the formula of C from the following ?

1. CuSO\(_4\)

2. [Cu(NH\(_3\))\(_4\)]\(^{2+}\)

3. Cu(OH)\(_2\)

4. CuCO\(_3\cdot\)Cu(OH)\(_2\)

1 answer

Best answer

Answer: 2. [Cu(NH\(_3\))\(_4\)]\(^{2+}\)

  1. Urea + water: \(\mathrm{NH_2CONH_2+2H_2O\rightarrow(NH_4)_2CO_3}\) (A).
  2. On decomposition: \(\mathrm{(NH_4)_2CO_3\rightarrow 2NH_3+CO_2+H_2O}\); B is \(\mathrm{NH_3}\).
  3. \(\mathrm{NH_3}\) with \(\mathrm{Cu^{2+}}\) gives the deep blue complex \(\mathrm{[Cu(NH_3)_4]^{2+}}\) (C).

Answer: option (2).

Doubtly AI · 30 Oct 2026 AI-generated · not yet verified Report
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