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Topic: Benzene: structure and aromaticity· Hydrocarbons

Consider the following compounds/species :i. naphthalene ii. cyclopentadienyl anion iii. cyclobutadiene iv. cyclopropenyl anion v. cyclopropenyl cation vi. cyclooctatetraene vii. anthracene (all drawn as structures)The number of compounds/species whi…

Consider the following compounds/species :

i. naphthalene ii. cyclopentadienyl anion iii. cyclobutadiene iv. cyclopropenyl anion v. cyclopropenyl cation vi. cyclooctatetraene vii. anthracene (all drawn as structures)

The number of compounds/species which obey Huckel's rule is ________.

seven structures i-vii

1. 5

2. 4

3. 6

4. 2

1 answer

Best answer

Answer: 2. 4

Key idea: Hückel's rule: a planar, cyclic, fully conjugated species with \((4n+2)\,\pi\) electrons is aromatic.

  • i. Naphthalene: 10 \(\pi\) e\(^-\): obeys.
  • ii. Cyclopentadienyl anion: 6 \(\pi\) e\(^-\): obeys.
  • iii. Cyclobutadiene: 4 \(\pi\) e\(^-\): no.
  • iv. Cyclopropenyl anion: 4 \(\pi\) e\(^-\): no.
  • v. Cyclopropenyl cation: 2 \(\pi\) e\(^-\): obeys.
  • vi. Cyclooctatetraene: 8 \(\pi\) e\(^-\) and non-planar: no.
  • vii. Anthracene: 14 \(\pi\) e\(^-\): obeys.

Four species obey: option 2.

Doubtly AI · 30 Oct 2026 AI-generated · not yet verified Report
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