Anisole reacts with HI at 398K to form –
Q.1 (ii) Anisole reacts with HI at 398K to form –
A. cyclohexanol
B. benzenol
C. iodobenzene
D. benzene
Q.1 (ii) Anisole reacts with HI at 398K to form –
A. cyclohexanol
B. benzenol
C. iodobenzene
D. benzene
Best answer
Answer: B. benzenol
Answer: (b) benzenol
The O–CH3 bond is cleaved by HI. Because the O–C(aryl) bond has partial double-bond character, iodide attacks the methyl carbon, giving phenol (benzenol) and methyl iodide:
C6H5–O–CH3 + HI \(\xrightarrow{398\ \text{K}}\) C6H5OH + CH3I
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